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    Röntgenfluoreszenzanalyse in der Laborpraxis

    Röntgenfluoreszenzanalyse in der Laborpraxis

    Autoren:

    Verlag:
    Wiley-VCH   Weitere Titel dieses Verlages anzeigen

    Erschienen: März 2017
    Seiten: 459
    Sprache: Deutsch
    Preis: 84.90 €
    Illustration: 140 schwarz-weiße und 30 farbige Abbildungen
    Maße: 246x175x27
    Einband: Taschenbuch
    ISBN: 9783527342921

    Inhaltsverzeichnis

    Einführung GRUNDLAGEN DER RÖNTGENSPEKTROSKOPIE Analytische Leistungsfähigkeit Röntgenstrahlung und deren Wechselwirkung Die Entwicklung der Röntgenspektroskopie Durchführung einer Analyse PROBENPRÄPARATION Ziele der Probenpräparation Präparationstechniken Präparation kompakter und homogener Materialien Kleinteilige Materialien Flüssige Proben Biologische Materialien Stäube und Aerosole GERÄTETYPEN FÜR DIE RÖNTGENFLUORESZENZANALYSE Genereller Aufbau eines Röntgenspektrometers Vergleich von wellenlängen- und energiedispersiven Gerätesystemen Geräteklassen Kommerziell verfügbare Gerätetypen MESSUNG UND AUSWERTUNG VON RÖNTGENSPEKTREN Informationsgehalt der Spektren Schritte bei der Durchführung der Messungen Auswahl der Messbedingungen Bestimmung der Peakintensität Quantifizierungsmodelle Schichtcharakterisierungen Chemometrische Methoden zur Materialcharakterisierung Erstellung einer Applikation ANALYSENFEHLER Generelle Betrachtungen Fehlerarten Berücksichtigung systematischer Fehler Fehlerangaben WEITERE ELEMENT-ANALYSEMETHODEN Übersicht Atomabsorptions-Spektroskopie Optische Emissionsspektroskopie Massenspektroskopie Röntgenspektroskopie mit Teilchenanregung Vergleich der Methoden STRAHLENSCHUTZ Physikalische Grundlagen Wirkungen ionisierender Strahlung auf menschliches Gewebe Natürliche Strahlenbelastungen Strahlenschutztechnische Regelungen ANALYSE HOMOGENER FESTPROBEN Eisenlegierungen Nickel-Eisen-Cobalt-Legierungen Kupferlegierungen Aluminiumlegierungen Sondermetalle Edelmetalle Gläser Kunststoffe Abriebanalyse ANALYSE PULVERFÖRMIGER PROBEN Geologische Proben Erze Böden und Klärschlämme Quarzsand Zement Kohle und Koks Ferrolegierungen Schlacken Keramik und Feuerfestmaterialien Stäube Nahrungsmittel Pharmaka Sekundärbrennstoffe ANALYSE VON FLÜSSIGKEITEN Multielementanalyse an Flüssigkeiten Kraftstoffe und Öle Spurenanalytik in Flüssigkeiten Spezielle Präparation von Flüssigkeitsproben SPURENANALYSE MIT TOTALREFLEXION Besonderheiten der Totalreflexionsröntgenfluoreszenz Probenpräparation für die Totalreflexionsröntgenfluoreszenz Auswertung der Spektren Typische Applikationen der TXRF INHOMOGENE PROBEN Messmodi Gerätetechnische Anforderungen Datenaufbereitung SCHICHTANALYTIK Analytische Aufgabenstellung Probenbehandlung Messtechnik Analysenbeispiele für Schichtsysteme PUNKTANALYSEN Partikelanalyse Chemometrische Identifizierung von Glaspartikeln Identifizierung von Einschlüssen Materialidentifizierung mit Handheld-Geräten Bestimmung toxischer Elemente in Konsumgütern - Restriction-of-hazardous-substances-Überwachung Toxische Elemente in Spielzeugen - Spielzeugverordnung ANALYSE VON ELEMENTVERTEILUNGEN Allgemeine Bemerkungen Messbedingungen Geologie Elektronik Archäometrische Untersuchungen Homogenitätstests SPEZIELLE ANWENDUNGEN DER RÖNTGENFLUORESZENZ Kombinatorik und High-throughput-Screening Chemometrische Spektrenauswertung Speziationsanalysen PROZESSKONTROLLE UND AUTOMATION Generelle Zielstellungen Offline- und Atline-Analytik Inline- und Online-Analytik QUALITÄTSMANAGEMENT UND VALIDIERUNG Motivation Validierung